The effect of partial replacement of natural filler by ground waste sulfur originated from the oil refining process on fresh and hardened properties of self-compacting concrete was investigated. Properties investigated were slump flow, V-funnel, L-box, and sieve segregation of fresh concrete mixes; and compressive, flexural, and bond (pull off) strengths, dynamic modulus of elasticity, ultrasonic pulse velocity, dynamic Poisson’s ratio, specific electrical resistance, density, and microstructure of hardened concrete. Results showed a slight decline in compressive, flexural, and bond strengths and dynamic elasticity modulus with increased addition of sulfur. Specific electrical resistance and density were higher for samples containing sulfur. Also, scanning electron microscopy indicated a slight porosity increase of the samples containing sulfur. Having in mind that, in the case of waste valorization in concrete, all properties of self-placing concrete should remain within acceptable levels or improve, this study proved that mixtures containing ground sulfur as a partial replacement for filler can be used for structural applications

Austenitic stainless steel is mostly used at high temperatures. It is known that during heating of the austenitic stainless steel with increasing temperature and time of annealing a microstructure is changed i.e. there is the precipitation of carbides followed by precipitation of secondary phases as a sigma phase. The presence of the delta ferrite in austenitic stainless steel enhances the formation of the sigma phase. This study represents the influence of delta ferrite on the sigma phase formation and the effect of the sigma phase on general corrosion. Corrosion tests were conducted in the corrosion cell according to Standard ASTM G5, on instrument potentiostat/galvanostat, Princeton Applied Research, model 263A-2, with the software PowerCORR® (Standard, ASTM G5-94). Examinations were carried out in 1% HCl and 10% FeCl3 solutions. Tafel extrapolation method was used for the investigation of general corrosion. The results of corrosion testing indicated that the intensity of the general corrosion increases with the increase of the delta ferrite and sigma phase contents.

Leachate water from sanitary landfills represents one of the most complex global environmental problems. This paper examines the possibility of using aluminosilicate material, pyrophyllite, from the Parsovići deposit, as an adsorbent. It was researched the influence of two granulations of pyrophyllite (0-53 μm and 0-100 μm) on the degree of adsorption of heavy metals (Fe, Ni, Mn) from leachate water from the municipal landfill "Desetine", Tuzla. The adsorption experiment was performed using the Batch method, depending on the contact time between the adsorbent and the adsorbate, the mixing speed, and the mass of the adsorbent, pyrophyllite, through two treatments. The results indicate a higher efficiency of the finer fraction of pyrophyllite, and in the competition of the three examined metals, iron is completely removed in the first treatment with both granulations and then nickel with finer granulation and manganese with coarser. After the first treatment, the unpleasant smell was removed, which is certainly a consequence of the removal of ammonia compounds as the most abundant compounds in leachate water. In these pioneering researches, pyrophyllite proved to be effective, and at the same time, it is a cheap, easily available, and environmentally friendly material for leachate water purification.